Product ID:X-40 FOAM PART A, RT-5080-A
MSDS Date:08/01/1989
FSC:8030
NIIN:00N027857
Kit Part:Y
MSDS Number: BMVGF

RESIN TECHNOLOGY CO

2270 CASTLE HARBOR PLACE
ONTARIO, CA 91761
US

Emergency Phone: 714-947-7224

Info Phone: 714-947-7224

Cage: RTECH

RESIN TECHNOLOGY CO

ONTARIO, CA 91761 US

Telephone: 714-947-7224

Cage: RTECH

SCBA. AIR PURIFYING (CARTRIDGE TYPE) RESPIRATORS

RTECS: 9999999ZZ

MAY NEED TO BE CLEANED BY SCRUBBERS/FILTERS TO REDUCE

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HAVE EXCELLENT RESISTANCE. OTHER MATLS SUCH AS

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TO "GUIDELINES FOR SELECTION OF CHEMICAL PROTECTIVE

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SHOWER IN WORK AREA.

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AIR RESPIRATOR W/FULL FCPIECE/AIR-SUPPLIED HOOD.

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POLYMETHYLENE POLYPHENYL ISOCYANATE; (SIMILAR STRUCTURE

CAS: 9016-87-9

RTECS: TR0350000

Fraction By Weight: 50%

CHEST W/DFCLTY BRTHG. SYMPS MAY BE IMMED/DELAYED

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CHRONIC EXPOSURES MAY RESULT IN PERM DECREASES IN

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REMOVE VICTIM TO FRESH AIR. IF NOT BRTHG,

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LABORED, GIVE OXYGEN. CONSULT MEDICAL PERSONNEL.

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WATER(5-10% SODIUM CARBONATE MAY BE SUBSTITUTED

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SOLN, USING 10 PARTS SOLN TO EACH PART SPILL & ALLOW

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LEAVING INSOLUBLE POLYUREAS. FOR MAJOR SPILLS, CALL

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DRUMS MUST BE DECONTAMD IN

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ISOCYANATE VAPS. SPRAY/POUR 5-15 LITERS OF DECONTAM

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LEAVE DRUM SOAKING UNSEALED FOR 48 HRS. POUR OUT

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OTHERWISE DESTROY RINSED CONTAINER BEFORE DISPOSAL.

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ISOCYANATES. THESE INDIVIDUALS SHOULD BE

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FURTHER EXPOS. MED EXAM SHLD INCLUDE MED HISTORY,

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ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (MDI)

CAS: 101-68-8

RTECS: NQ9350000

Fraction By Weight: 50%

OSHA PEL 0.02 PPM, C

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:LD50: (ORAL,RAT) >10,000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST: SINGLE DOSE OF PROD IS
PRACTICALLY NONTOXIC BY INGEST. IRRIT OF MOUTH, PHARYNX, ESOPHAGUS
& STOMACH CAN DEVELOP FOLLOWING INGEST. EYE: MATL WILL PROBABLY
IRRIT HUMAN EYES FOLLOWING CONTACT. SK IN: NO IRRIT IS LIKELY
FOLLOWING SHORT CONTACT PERIODS W/HUMAN SKIN. SKIN SENSIT & IRRIT
MAY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: DEVEL AFTER RPTD/PRLNG CONT W/HUMAN
SKIN. PRLNG/RPTD SKIN CONT W/MDI CAN INDUCE DELAYED SKIN RXNS SEV
HOURS AFTER EXPOS. INHAL: VAPS/AEROSOLS CAN IRRIT EYES,NOSE & RESP
PASSAGES. SEVERE OVER EXP MAY LEAD TO PULM EDEMA. MDI CAN INDUCE
RESP SENSIT W/ASTHMA-LIKE SYMPS SIMILAR TO THOSE INDUCED BY (SUPP
DATA)
Medical Cond Aggravated by Exposure:PREVIOUSLY SENSITIZED INDIVIDUALS
OR TO INDIVIDUALS WITH EXISTING RESPIRATORY DISEASE, SUCH AS
CHRONIC BRONCHITIS, EMPHYSEMA, ASTHMA. SENSITIZED INDIVIDUALS SHLD
BE REMOVED FROM ANY FURTHER EXPOSURE.

First Aid:SKIN: WASH MATL OFF OF SKIN W/PLENTY OF SOAP & WATER. IF
REDNESS, ITCHING, OR BURNING SENSIT DEVELS, GET MED ATTN. EYES:
IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. IF REDNESS,
ITCHING, BURNIN G SENSATION DEVEL, HAVE EYES EXAMINED &TREATED BY
MED PERS. INGEST: GIVE 1-2 GLASSES OF WATER TO DRINK. IF GI SYMPS
DEVEL, CONSULT MD. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS.
INHAL: (ING 5)

Flash Point Method:COC
Flash Point:425F,218C
Extinguishing Media:DRY CHEM, FOAM, CO*2, HALOGENATED AGENTS. IF H*2O
IS USED,USE VERY LGE QTYS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . THE REACTION BETWEEN WATER & HOT ISOCYANATE
MAY BE VIGOROUS.
Unusual Fire/Explosion Hazard:WATER CONTAMINATION WILL PRODUCE CO*2. DO
NOT RESEAL CONTAMINATED CONTAINERS AS PRESSURE BUILDUP MAY RUPTURE
THEM.

Spill Release Procedures:WEAR SKIN, EYE, & RESP PROT DURING CLEANUP.
SOAK UP MATL W/ABSORB & SHOVEL INTO A CHEM WASTE CNTNR. COVER
CNTNR, BUT DO NOT SEAL & REMOVE FROM WORK AREA. PREPARE A DECONTAM
SOLUTION OF 0.2-5% LIQ DETE RGENT & 3-8% CONC AMMONIUM HYDROXIDE
IN(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN TIGHTLY SEALED CNTNRS TO PROT
FROM ATMOS MOISTURE. STORE IN COOL AREA. PVNT SKIN/EYE CONTACT.
AVOID BRTHG VAPS/AEROSOLS. OBSERVE TLV LMTS.
Other Precautions:WORKERS SHLD SHOWER & CHANGE TO FRESH CLTHG AFTER
EACH SHIFT. SENSITIZED INDIVID SHLD NOT BE EXPOS TO PROD WHICH
CAUSED SENSIT. INDIVIDUALS W/EXISTING RESP DISEASE SUCH AS CHRONIC
BRONCHITIS, EMPHYSEM A/ASTHMA SHLD NOT BE EXPOS TO (ING 14)

Respiratory Protection:BECAUSE OF LOW VAP PRESS, VENT IS USUALLY
SUFFICIENT TO KEEP VAPS MATLS ARE SPRAYED/HEATED. IF AIRBORNE CONCS EXCEED/ARE EXPECTED TO
EXCEED TLV, USE NIOSH/MSHA APPRVD POSITIVE PRESS SUPPLIED (ING 16)
Ventilation:USE LOC EXHST VENT TO KEEP AIRBORNE CONC GUIDELINES IN ACGIH PUB "INDUSTRIAL VENT". EXHST AIR (ING 18)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEM WORK GOGS & FULL LNGTH FCSHLD
Other Protective Equipment:APRON-ARM COVERS-FULL BODY SUIT CONSTRUCTED
OF BUTYL/NITRILE RUBBER/SARANEX COATED TYVEK/SOME NEOPRENE GARMENTS
(ING 19)
Work Hygienic Practices:WASH CONTAMD CLOTHING BEFORE REWEARING.
Supplemental Safety and Health
BOIL PT:646F,341C(DECOMP). MATL TO AVOID:W/H*2O IS VERY SLOW <50C, BUT
ACCELS AT >TEMPS & IN PRESENCE OF ALKALIES/TERTIARY AMINES/METAL
CMPDS. SOME RXNS CAN BE VIOLENT. CNDTNS TO AVOID(POLY): OF CO*2
GAS MAY RUPTURE CLSD CNTNRS. EFTS OF OVEREXP: TDI (TOLUENE
DIISOCYANATE). SYMPS INCL CHRONIC COUGH, TIGHTNESS OF (ING 3)

HCC:N1
Boiling Pt:B.P. Text:646F,341C
Vapor Pres:<.0001@20C
Vapor Density:8.6
Spec Gravity:1.2
Solubility in Water:REACTS
Appearance and Odor:DARK BROWN, VISCOUS LIQUID WITH SLIGHT ODOR.

Stability Indicator/Materials to Avoid:YES
WILL REACT W/ANY MTLS CNTNG ACTIVE HYDROGENS, E.G., H*2O, ALCOHOL,
AMMONIA, AMINES, ALKALIES & ACIDS. THE RXN(SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUST PRODS: CO*2, CO, NITROGEN
OXIDES, AMMONIA. TRACE AMOUNTS OF HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:HIGH TEMPS IN PRESENCE OF ALKALIES,
TERTIARY AMINES, & METAL CMPDS WILL ACCELERATE POLYMERIZATION. POSS
EVOL (SUPP DATA)

Waste Disposal Methods:SLOWLY STIR ISOCYANATE WASTE INTO DECOMTAM SOLN
USING 10 PARTS SOLN FOR EACH PART ISOCYANATE. LET STAND FOR 48 HRS,
ALLOWING EVOLVED CO*2 TO VENT AWAY. NEUT WASTE. NEITHER SOLID NOR
LIQ PORTION IS HAZ WASTE UNDER RCRA, 40 CFR 261. (ING 10)

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particular situation.